309C: NMR Spectroscopy in Organic Chemistry
Handout 1
Return to Answers for Question Sheet 3

NMR Properties of commonly observed nuclei



Isotope Spin Natural Abundance
%
Magnetogyric Ratio
(x107rad/T/s)
NMRa
Frequency MHz
2.3488T
NMRb
Frequency MHz
11.744T
Usual Reference Compound

1H 1/2 99.98 26.75 100.00 500.00 TMS
2H 1 0.015 4.11 15.35 76.75 TMS
10B 3 19.58 2.87 10.75 53.73 BF3.OEt2
11B 3/2 80.42 8.58 32.08 160.42 BF3.OEt2
13C 1/2 1.108 6.73 25.14 125.72 TMS
14N 1 99.63 1.93 7.22 36.12 NH3.NO3- or MeNO2
15N 1/2 0.37 -2.71 10.13 50.66 NH3.NO3- or MeNO2
17O 5/2 0.0037 -3.63 13.56 67.78 H2O
19F 1/2 100.0 25.17 94.08 470.39 CCl3F
23Na 3/2 100.0 7.08 26.45 132.26 1M NaCl/H2O
27Al 5/2 100.0 6.97 26.06 130.29 [Al(H2O)6]3+
29Si 1/2 4.7 -5.31 19.86 99.32 TMS
31P 1/2 100.0 10.83 40.48 202.40 H3PO4 85%
119Sn 1/2 8.58 9.97 37.27 186.36 Me4Sn
195Pt 1/2 33.8 5.75 21.50 107.49 PtCl62- or [Pt(CN)6]2-
207Pb 1/2 22.6 5.60 20.92 104.61 Me4Pb


It is common to refer to an NMR instrument by the resonance frequency of 1H nuclei (e.g.a 200 MHz spectrometer observes 1H at 200 MHz), but realise that the instrument could observe other NMR-active nuclei by using a different frequency.